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Iron Hydride in the Earth's Inner Core and Its Geophysical Implications

Hua Yang, Joshua Muir, Feiwu Zhang

2022Geochemistry Geophysics Geosystems12 citationsDOIOpen Access PDF

Abstract

Abstract Hydrogen is potentially a key light element in the Earth's core. Determining the stability of iron hydride is essential for Earth's core mineralogy applications. We investigated the thermal stabilities of a range of Fe‐H binaries at core P ‐ T conditions. It is concluded that face‐centered cubic phase FeH is stable in the Earth's inner core. The high mobility of hydrogen in the Fe lattice suggests that hydrogen is transferred to a superionic state under the inner core conditions, where the superionic state transfer temperature of H in Fe fcc lattice is ∼500 K higher than that in hcp Fe system. The H concentration in the inner core is estimated to be ∼0.92 wt% to explain its density deficit, this value was further constrained to ∼0.21 wt% by matching the density jump at the inner‐core boundary. H alongside other light elements are required to account for the geophysical observations of the Earth's inner core.

Topics & Concepts

Inner coreOuter coreHydrogenHydrideEarth (classical element)Mantle (geology)Lattice (music)GeophysicsCore (optical fiber)GeologyMineralogyChemical physicsMaterials scienceChemistryPhysicsAcousticsComposite materialMathematical physicsOrganic chemistryHigh-pressure geophysics and materialsGeological and Geochemical AnalysisGeomagnetism and Paleomagnetism Studies