<b>Improvement in hydrogen storage performance of MgH</b> <sub> <b>2</b> </sub> <b>by vanadium doped with ZIF‐8 derived a single‐atom catalyst</b> V–N–C
Feifan Hong, Weitao Shi, Ruolin Zhao, Yi Fan, Ziqi Liu, Sizhi Ding, Haizhen Liu, Wenzheng Zhou, Jin Guo, Zhiqiang Lan
Abstract
Abstract Herein, the successful preparation of a single‐atom catalyst V–N–C using vanadium‐doped zeolitic imidazolate framework (ZIF)‐8 as a precursor is reported. The experimental results showed that the V–N–C had a good promoting effect on the hydrogen storage performance of MgH 2 , and the optimal addition amount of V–N–C was 10 wt%. The hydrogenation and dehydrogenation apparent activation energies of 10 wt% V–N–C‐catalyzed MgH 2 were reduced by 44.9 and 53.5 kJ·mol −1 , respectively, compared to those of additive‐free MgH 2 . The 10 wt% V–N–C‐catalyzed MgH 2 could reabsorb 5.92 wt% of hydrogen in 50 min at 150 °C, with a capacity retention rate of 99.1% after 30 cycles of hydrogen absorption and desorption. Mechanism analysis showed that V–N–C was partially transformed into VN and metallic V when it was milled with MgH 2 ; the in‐situ‐formed VN and metallic V played an important role in improving the hydrogen storage performance of MgH 2 . This approach provides a potential solution for obtaining high‐performance Mg‐based hydrogen storage materials through synergistic interactions between V, N and C.