Ligand‐Mediated Revival of Degraded α‐CsPbI <sub>3</sub> to Stable Highly Luminescent Perovskite
Arup Ghorai, Somnath Mahato, Sudarshan Singh, Shaona Bose, Baidyanath Roy, Unyong Jeong, S. K. Ray
Abstract
Abstract Although α‐CsPbI 3 is regarded as an attractive optical luminophore, it is readily degraded to the optically inactive δ‐phase under ambient conditions. Here, we present a simple approach to revive degraded (“optically sick”) α‐CsPbI 3 through “medication” with thiol‐containing ligands. The effect of different types of thiols is systematically studied through optical spectroscopy. The structural reconstruction of degraded α‐CsPbI 3 nanocrystals to cubic crystals in the presence of thiol‐containing ligands is visualized through high‐resolution transmission electron microscopy and supported by X‐ray diffraction analysis. We found that 1‐dodecanethiol (DSH) effectively revives degraded CsPbI 3 and results in high immunity towards moisture and oxygen, hitherto unreported. DSH facilitates the passivation of surface defects and etching of degraded Cs 4 PbI 6 phase, thus reverting them back to the cubic CsPbI 3 phase, leading to enhanced PL and environmental stability.