Disclosing the Interaction between Carbon Monoxide and Alkylated Ti<sup>3+</sup> Species: a Direct Insight into Ziegler–Natta Catalysis
Alessandro Piovano, Jelena Zarupski, Elena Groppo
Abstract
-alkyl bond, both in the absence and in the presence of the olefin monomer. In perspective, this has important implications for the characterization of the active sites in industrial Ziegler-Natta catalysts, even under working conditions.
Topics & Concepts
NattaCatalysisCarbon monoxideOlefin fiberPolymerizationAlkylationAlkylChemistryOlefin polymerizationTitaniumZiegler–Natta catalystMonomerPhotochemistryPolymer chemistryOrganic chemistryPolymerEthyleneOrganometallic Complex Synthesis and CatalysisCarbon dioxide utilization in catalysisIonic liquids properties and applications