Zr-Based Metal–Organic Framework with Wall-Shared Dual Ultramicroporous Channels for Effective CH<sub>4</sub>/N<sub>2</sub> Separation
Rundao Chen, Jiaqi Li, Fangru Zhou, Bin Sheng, Haoran Sun, Fang Zheng, Qiwei Yang, Zhiguo Zhang, Qilong Ren, Zongbi Bao
Abstract
The adsorptive separation of methane (CH 4 ) and nitrogen (N 2 ) is a challenging yet crucial process in the purification of unconventional natural gas. In this work, we report a robust Zr-based metal–organic framework, termed as MIP-203-F, for the selective adsorption of CH 4 from CH 4 /N 2 mixtures with varied concentrations. The framework possesses a rhombic one-dimensional (1D) micropore structure that is effectively divided into two symmetric wall-shared triangular pores by the presence of pendent −OH groups, which endow the material with an optimal pore size and a plethora of synergistic polar sites, facilitating the efficient adsorption of CH 4 with a high polarizability and overcoming the trade-off between CH 4 capacity and CH 4 /N 2 selectivity. The exceptional separation performance of MIP-203-F was validated through comprehensive experimental investigations encompassing thermodynamic analyses, breakthrough experiments, and theoretical calculations. These findings underscore the immense potential of MIP-203-F as a promising candidate for the adsorptive separation of CH 4 /N 2 .