MnBr(CO)<sub>5</sub>: a commercially available highly active catalyst for olefin hydrosilylation under ambient air and green conditions
Anthony Vivien, Laurent Veyre, Raphaël Mirgalet, Clément Camp, Chloé Thieuleux
Abstract
Commercially available MnBr(CO) 5 was found to be a remarkable catalyst for olefin hydrosilylation reactions using a wide range of olefins and silanes. This system tolerates unpurified substrates and can be used in green solvents under ambient air.
Topics & Concepts
HydrosilylationOlefin fiberCatalysisSilanesMaterials scienceRange (aeronautics)Chemical engineeringChemistryOrganic chemistryComposite materialSilaneEngineeringCarbon dioxide utilization in catalysisChemical Synthesis and ReactionsAsymmetric Hydrogenation and Catalysis