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NiO‐Co<sub>3</sub>O<sub>4</sub>‐rGO as an Efficient Electrode Material for Supercapacitors and Direct Alcoholic Fuel Cells

Mohammad Bagher Askari, Parisa Salarizadeh, Amirkhosro Beheshti‐Marnani, Antonio Di Bartolomeo

2021Advanced Materials Interfaces127 citationsDOIOpen Access PDF

Abstract

Abstract Transition metal oxides can be performant electrode materials for supercapacitors and alcohol oxidation if their conductivity and capacity are improved. Herein, an advanced nanocomposite material made of NiO‐Co 3 O 4 on reduced graphene oxide (rGO) is synthesized by a one‐step hydrothermal method for supercapacitors and methanol/ethanol oxidation. It is demonstrated that the nanocomposite is a promising material for energy storage as NiO‐Co 3 O 4 ‐rGO supercapacitor electrodes achieve a specific capacity of 149 mAh g −1 (894 F g −1 ) at a current density of 0.5 A g −1 , the discharge time of 689 s, and excellent stability of 95% after 6000 cycles. Moreover, NiO‐Co 3 O 4 ‐rGO shows a current density of 15 and 10 mA cm −2 in methanol and ethanol oxidation reactions, respectively, along with excellent stability.

Topics & Concepts

SupercapacitorMaterials scienceNon-blocking I/ONanocompositeGrapheneOxideChemical engineeringElectrodeMethanolInorganic chemistryNanotechnologyElectrochemistryCatalysisMetallurgyOrganic chemistryChemistryPhysical chemistryEngineeringSupercapacitor Materials and FabricationAdvanced battery technologies researchElectrocatalysts for Energy Conversion
NiO‐Co<sub>3</sub>O<sub>4</sub>‐rGO as an Efficient Electrode Material for Supercapacitors and Direct Alcoholic Fuel Cells | Litcius