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3d-4f Resonant Inelastic X-ray Scattering of Actinide Dioxides: Crystal-Field Multiplet Description

Sergei M. Butorin

2020Inorganic Chemistry34 citationsDOIOpen Access PDF

Abstract

edges demonstrate overall better agreement between the HERFD and XAS spectra for most dioxides, keeping in mind a restricted HERFD resolution, because of the core-hole lifetime broadening in the final state. The results confirm the utility of HERFD for the An chemical state determination and indicate the importance of calculating the entire RIXS process in order to interpret the HERFD data correctly.

Topics & Concepts

ChemistryMultipletActinideX-rayField (mathematics)ScatteringInelastic scatteringResonant inelastic X-ray scatteringCrystal (programming language)Atomic physicsInelastic neutron scatteringNuclear physicsInorganic chemistryOpticsPhysicsSpectral lineProgramming languageAstronomyPure mathematicsComputer scienceMathematicsRadioactive element chemistry and processingNuclear materials and radiation effectsNuclear Materials and Properties