Zero-Quantum-Defect Method and the Fundamental Vibrational Interval of <mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML" display="inline"><mml:mrow><mml:msubsup><mml:mrow><mml:mi mathvariant="normal">H</mml:mi></mml:mrow><mml:mrow><mml:mn>2</mml:mn></mml:mrow><mml:mrow><mml:mo>+</mml:mo></mml:mrow></mml:msubsup></mml:mrow></mml:math>
I. Doran, Nicolas Hölsch, Maximilian Beyer, F. Merkt
Abstract
The fundamental vibrational interval of H_{2}^{+} has been determined to be ΔG_{1/2}=2191.126 614(17) cm^{-1} by continuous-wave laser spectroscopy of Stark manifolds of Rydberg states of H_{2} with the H_{2}^{+} ion core in the ground and first vibrationally excited states. Extrapolation of the Stark shifts to zero field yields the zero-quantum-defect positions -R_{H_{2}}/n^{2}, from which ionization energies can be determined. Our new result represents a 4-order-of-magnitude improvement compared to earlier measurements. It agrees, within the experimental uncertainty, with the value of 2191.126 626 344(17)(100) cm^{-1} determined in nonrelativistic quantum electrodynamic calculations [V. Korobov, L. Hilico and J.-Ph. Karr, Phys. Rev. Lett. 118, 233001 (2017)PRLTAO0031-900710.1103/PhysRevLett.118.233001].