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Thin Ga-doped ZnO Film with Enhanced Dual Visible Lines Emission

Sanaz Alamdari, Mohammad Reza Mansourian, Morteza Sasani Ghamsari

2023Current Nanomaterials11 citationsDOI

Abstract

Introduction: In this study, a simple and facile route was employed to prepare a highly transparent and luminescent ultra-thin gallium doped ZnO film (GZO). Methods: The thin GZO film has been deposited using the simultaneously ultrasonic vibration and sol-gel spin-spray coating technique. The structural and optical properties of pure and doped thin films were investigated by various methods, such as X-ray diffraction (XRD), X-ray photoemission spectroscopy (XPS), scanning electron microscopy (SEM), UV-Vis, and PL spectroscopy. Results: XRD results indicated that both pure and doped ZnO films had a hexagonal wurtzite structure with (101) preferred orientation. XPS and EDX studies confirmed the incorporation and presence of Ga ions into the ZnO lattice structure. The doped sample showed nearly 90% of transparency, and a strong blue-green emission in the visible region. Conclusion: The obtained results proved that the prepared thin film could be a novel candidate for optoelectronic applications.

Topics & Concepts

Wurtzite crystal structureMaterials scienceX-ray photoelectron spectroscopyThin filmDopingScanning electron microscopeSpin coatingGalliumAnalytical Chemistry (journal)SpectroscopyOptoelectronicsNanotechnologyChemical engineeringZincComposite materialChemistryEngineeringPhysicsQuantum mechanicsChromatographyMetallurgyZnO doping and properties
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