Engineering geometric metamorphosis in {P<sub>6</sub>M<sub>2</sub>Mo<sub>16</sub>O<sub>73</sub>}-based high-nuclearity metal superclusters: from tetrahedral to square assemblies <i>via</i> topological transformations
Xiaoyan Zhang, Hui Li, Na Xu, Xiaodong Liu, Xiuli Wang
Abstract
The precision engineering of the molecular framework has synthesized two superclusters based on the {Sr⊂P 6 M 2 Mo 16 O 73 } motif, which exhibit closely related topological structures: Co12Sr4Mo80P36 and Na4Ni23Sr4Mo88P52.
Topics & Concepts
TetrahedronSquare (algebra)CrystallographyMetalMaterials sciencePhysicsChemistryMineralogyMetallurgyGeometryMathematicsPolyoxometalates: Synthesis and ApplicationsMetal-Organic Frameworks: Synthesis and ApplicationsNanocluster Synthesis and Applications