Hydrogen diffusivity, uptake and embrittlement of solution annealed and cold deformed austenitic stainless steel 1.4435 at hydrogen pressures up to 1000 bar and 200 °C
Matthias Eichinger, Johann Pengg, Dino Zwittnig, Gregor Mori
Abstract
Austenitic stainless steel 1.4435, a candidate material for high-pressure tubing for hydrogen applications, was investigated in two different stages of cold deformation (0 and 27 %) regarding its hydrogen embrittlement tendency. The determination of effective diffusion coefficients revealed slightly increased diffusion kinetics at 60°C for the cold-reduced material (8.0 · 10 −15 m²/s) compared to the solution annealed one (5.0 · 10 −15 m²/s). High-pressure gaseous hydrogen charging shows no differences regarding the degree of cold deformation with a maximum hydrogen concentration of 112 wt.-ppm. Furthermore, a significant ductility loss expressed by the ratio of the reduction of area was observed. • Cold drawn material shows enhanced diffusion kinetics than solution annealed state. • Hydrogen contents of up to 112 wt.-ppm are present after gaseous charging. • No failure occurred in constant load tests at 90 % of the yield strength. • SSRTs show no significant decrease in fracture elongation due to hydrogen charging. • 1.4435 is applicable for hydrogen tank systems within the tested conditions.