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Palladium-mediated C–O bond activation of benzopyrone in 4-oxo-4<i>H</i>-chromone-3-carbaldehyde-4(<i>N</i>)-substituted thiosemicarbazone: synthesis, structure, nucleic acid/albumin interaction, DNA cleavage, antioxidant and cytotoxic studies

A. Shanmugapriya, G. Kalaiarasi, Maddaly Ravi, Hazel A. Sparkes, P. Kalaivani, R. Prabhakaran

2021New Journal of Chemistry15 citationsDOIOpen Access PDF

Abstract

Palladium ion-mediated C–O activation at the C2 carbon of the benzopyrone moiety of 3-formylchromone-4( N )-substituted thiosemicarbazone (HL1–4) has been observed in square-planar palladium( ii ) complexes.

Topics & Concepts

ChemistryPalladiumSemicarbazoneMoietyNucleic acidStereochemistryCleavage (geology)Medicinal chemistryCatalysisOrganic chemistryBiochemistryEngineeringFracture (geology)Geotechnical engineeringMetal complexes synthesis and propertiesSynthesis of Organic CompoundsLanthanide and Transition Metal Complexes
Palladium-mediated C–O bond activation of benzopyrone in 4-oxo-4<i>H</i>-chromone-3-carbaldehyde-4(<i>N</i>)-substituted thiosemicarbazone: synthesis, structure, nucleic acid/albumin interaction, DNA cleavage, antioxidant and cytotoxic studies | Litcius