Correlating axial and equatorial ligand field effects to the single-molecule magnet performances of a family of dysprosium bis-methanediide complexes
Lewis R. Thomas‐Hargreaves, Marcus J. Giansiracusa, Matthew Gregson, Emanuele Zanda, Felix O’Donnell, Ashley J. Wooles, Nicholas F. Chilton, Stephen T. Liddle
Abstract
Studies on equatorial donor and CDyC angle variation effects on energy barriers to the slow relaxation of magnetisation are reported.
Topics & Concepts
DysprosiumSingle-molecule magnetMagnetRelaxation (psychology)MagnetizationField (mathematics)CrystallographyLanthanideLigand field theoryLigand (biochemistry)MoleculeMolecular magnetsMaterials scienceCondensed matter physicsMagnetic relaxationChemistryNuclear magnetic resonanceChemical physicsMagnetic fieldPhysicsInorganic chemistryIonOrganic chemistryMathematicsPsychologyPure mathematicsReceptorSocial psychologyQuantum mechanicsBiochemistryMagnetism in coordination complexesLanthanide and Transition Metal ComplexesElectron Spin Resonance Studies