Extraction modeling, kinetics and thermodynamics of solvent extraction of Irvingia gabonensis kernel oil, for possible industrial application
Chinedu M. Agu, Matthew C. Menkiti, Pascal Ohale, Victor Ifeanyi Ugonabo
Abstract
Temperature, time and particle size effects on Irvingia gabonensis kernel oil (IGKO) yield, as well as the kinetics and thermodynamics parameters were investigated. Highest oil yield of 68.80 % (by weight) was obtained at 55 °C, 150 min., and 0.5 mm. Evaluated physicochemical properties of IGKO indicated that viscosity, acidity, dielectric strength, flash and pour points were 19.37 mm2s-1, 5.18 mg KOHg-1, 25.83 KV, 285 °C, and 17 °C, respectively, suggesting its feasibility as transformer fluid upon further treatment. Of the pseudo second order (PSO) and hyperbolic kinetic models studied, the former gave better fit to the experimental data. ∆H, ∆S and ∆G values of IGKO extraction at 0.5 mm and 328 K were, 251.81 KJ/mol, 1.08 KJ/mol and -105.49 KJ/mol, respectively, indicating the endothermic, irreversible and spontaneous nature of the process. Kinetic model equations that describe the process were successfully developed for both models based on the process parameters.