Perfluorinated gallium phthalocyanine axially grafted black phosphorus nanosheets for optical limiting
Zhiwei Liu, Bin Zhang, Ningning Dong, Jun Wang, Yu Chen
Abstract
Fluorine-containing gallium phthalocyanine (F<sub>16</sub>PcGa) axially grafted black phosphorus (BP) nanosheets (F<sub>16</sub>PcGa–BP) were synthesized by reaction of F<sub>16</sub>PcGaCl with 4-hydroxylbenzenediazonium tetrafluoroborate-functionalized BP (4-HBT-BP). In contrast to BP and F<sub>16</sub>PcGaCl, F<sub>16</sub>PcGa–BP exhibits better nonlinear optical and optical limiting responses at 532 nm.
Topics & Concepts
GalliumMaterials scienceBlack phosphorusAxial symmetryPhthalocyanineLimitingTetrafluoroboratePhosphorusInorganic chemistryNonlinear opticalPhysical chemistryAnalytical Chemistry (journal)CatalysisNanotechnologyOptoelectronicsOrganic chemistryIonic liquidChemistryNonlinear systemMetallurgyPhysicsEngineeringQuantum mechanicsMechanical engineeringNonlinear Optical Materials StudiesPorphyrin and Phthalocyanine ChemistryAdvanced Fiber Laser Technologies