Gold(<scp>i</scp>)-catalysed hydroarylations of alkynes for the synthesis of inherently chiral calix[4]arenes
Gabriele Giovanardi, Gabriele Scarica, Valentina Pirovano, Andrea Secchi, Gianpiero Cera
Abstract
-functionalisation of the calix[4]arene macrocycle, is able to deliver an ample family of N-heterocyclic, chiral compounds in high yields and functional group tolerance.
Topics & Concepts
ChemistryCombinatorial chemistryCalixareneStereochemistryOrganic chemistryMoleculeCatalytic Alkyne ReactionsCatalytic C–H Functionalization MethodsNanocluster Synthesis and Applications