Synthesis of Mesoionic N-Heterocyclic Olefins and Catalytic Application for Hydroboration Reactions
Zengyu Zhang, Shiqing Huang, Linwei Huang, Xingyu Xu, Hongyan Zhao, Xiaoyu Yan
Abstract
-heterocyclic olefins have been developed, which feature high ylidic character. These compounds have been used as efficient catalysts for hydroboration of imines, nitriles, and N-heteroarenes.
Topics & Concepts
MesoionicHydroborationChemistryCatalysisOrganic chemistryN-Heterocyclic Carbenes in Organic and Inorganic ChemistryOrganoboron and organosilicon chemistryCarbon dioxide utilization in catalysis