Mixing and matching <i>N</i>,<i>N</i>- and <i>N</i>,<i>O</i>-chelates in anionic Mg(<scp>i</scp>) compounds: synthesis and reactivity with RNCNR and CO
Andrea O’Reilly, Matthew D. Haynes, Zoë R. Turner, Claire L. McMullin, Sjoerd Harder, Dermot O’Hare, J. Robin Fulton, Martyn P. Coles
Abstract
Reduction of a bis(amidodimethyl)disiloxane Mg( ii ) compound affords a mixture of N , N - and N , O -chelated Mg( i ) species. Reactivity with RNCNR and CO demonstrate reducing behaviour, with the products showing a combination of ligands at magnesium.
Topics & Concepts
Reactivity (psychology)Mixing (physics)ChelationChemistryMedicinal chemistryOrganic chemistryPhysicsQuantum mechanicsPathologyAlternative medicineMedicineCoordination Chemistry and OrganometallicsSynthesis and characterization of novel inorganic/organometallic compoundsInorganic Chemistry and Materials