Chiral nickel(II) complex catalyzed asymmetric (3 + 2) cycloaddition of α‐diazo pyrazoleamides with 2‐siloxy‐1‐alkenes

Wei Yang, Zhendong Yang, Long Chen, Yican Lu, Cefei Zhang, Zhishan Su, Xiaohua Liu, Xiaoming Feng

2022Chinese Chemical Letters16 citationsDOI

Topics & Concepts

CarbenoidCycloadditionCatalysisEnantioselective synthesisDiazoChemistryEnolNickelAcetalMedicinal chemistryStereochemistryOrganic chemistryRhodiumCyclopropane Reaction MechanismsSynthesis and Catalytic ReactionsCatalytic C–H Functionalization Methods

Chiral nickel(II) complex catalyzed asymmetric (3 + 2) cycloaddition of α‐diazo pyrazoleamides with 2‐siloxy‐1‐alkenes

Topics & Concepts

Chiral nickel(II) complex catalyzed asymmetric (3 + 2) cycloaddition of α‐diazo pyrazoleamides with 2‐siloxy‐1‐alkenes