Selective Azidooxygenation of Alkenes Enabled by Photo-induced Radical Transfer Using Aryl-λ<sup>3</sup>-azidoiodane Species
Aakanksha Gurawa, M. Kumar, Sudhir Kashyap
Abstract
-azidoiodane species and cascade proceeding to generate an active carbon-centered radical. The late-stage transformations of azido- and oxy-moieties were amply highlighted by assembling high-value drug analogs and bioactive skeletons.
Topics & Concepts
VicinalChemistryIntermolecular forceArylPhotoredox catalysisPhotodissociationRadicalCatalysisPhotochemistryCombinatorial chemistryAryl radicalOrganic chemistryMoleculePhotocatalysisAlkylRadical Photochemical ReactionsOxidative Organic Chemistry ReactionsCatalytic C–H Functionalization Methods