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Electrically switchable metallic polymer nanoantennas

Julian Karst, Moritz Floess, Monika Ubl, Carsten Dingler, Claudia Malacrida, Tobias Steinle, Sabine Ludwigs, Mario Hentschel, Harald Gießen

2021Science172 citationsDOI

Abstract

Electrical switching of a metal-to-insulator transition would provide a building block for integrated electro-optically active plasmonics. In this work, we realize plasmonic nanoantennas from metallic polymers, which show well-pronounced localized plasmon resonances in their metallic state. As a result of the electrochemically driven optical metal-to-insulator transition of the polymer, the plasmonic resonances can be electrically switched fully off and back on at video-rate frequencies of up to 30 hertz by applying alternating voltages of only ±1 volt. With the use of this concept, we demonstrate electrically switchable beam-steering metasurfaces with a 100% contrast ratio in transmission. Our approach will help to realize ultrahigh efficiency plasmonic-based integrated active optical devices, including high-resolution augmented and virtual reality technologies.

Topics & Concepts

PlasmonMaterials scienceMetal-insulator-metalOptoelectronicsInsulator (electricity)PolymerVoltageTransmission (telecommunications)NanotechnologyOpticsComputer scienceTelecommunicationsElectrical engineeringPhysicsCapacitorEngineeringComposite materialPlasmonic and Surface Plasmon ResearchMetamaterials and Metasurfaces ApplicationsGold and Silver Nanoparticles Synthesis and Applications
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