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Nanoscale Design for High Entropy Alloy Electrocatalysts

Yanjie Li, Zhenpeng Yao, Wenpei Gao, Wen Shang, Tao Deng, Jianbo Wu

2023Small46 citationsDOIOpen Access PDF

Abstract

Due to their distinctive physical and chemical characteristics, high entropy alloys (HEAs), a class of alloys comprising multiple elements, have garnered a lot of attention. It is demonstrated recently that HEA electrocatalysts increase the activity and stability of several processes. In this paper, the most recent developments in HEA electrocatalysts research are reviewed, and the performance of HEAs in catalyzing key reactions in water electrolysis and fuel cells is summarized. In addition, the design strategies for HEA electrocatalysts optimization is introduced, which include component selection, size optimization, morphology control, structural engineering, crystal phase regulation, and theoretical prediction, which can guide component selection and structural design of HEA electrocatalysts.

Topics & Concepts

AlloyMaterials scienceHigh entropy alloysElectrolysisNanotechnologyNanoscopic scaleComponent (thermodynamics)Material DesignMetallurgyChemistryThermodynamicsElectrodeComposite materialPhysical chemistryElectrolytePhysicsElectrocatalysts for Energy ConversionHigh Entropy Alloys StudiesChalcogenide Semiconductor Thin Films