Expedient radical phosphonylations <i>via</i> ligand to metal charge transfer on bismuth
Jatin Patra, Akshay M. Nair, Chandra M. R. Volla
Abstract
Herein, we have developed efficient radical phosphonylations tailored upon visible-light mediated LMCT on bismuth. Phosphonylation of a broad range of substrate classes was carried out under mild energy efficient conditions using BiCl 3 as the catalyst.
Topics & Concepts
BismuthSubstrate (aquarium)Charge (physics)Ligand (biochemistry)Visible spectrumMetalCatalysisPhotochemistryRange (aeronautics)Materials scienceEnergy transferChemistryCombinatorial chemistryNanotechnologyOptoelectronicsChemical physicsOrganic chemistryPhysicsBiochemistryQuantum mechanicsOceanographyReceptorGeologyComposite materialRadical Photochemical ReactionsSulfur-Based Synthesis TechniquesCatalytic C–H Functionalization Methods