Hierarchical chiral MOFs with the induced chirality of AIE ligands exhibiting non-reciprocal CPL
Hong-Ru Fu, Dan‐Dan Ren, Kun Zhang, Shuang Wang, Xu-Jing Yang, Qing-Rong Ding, Ya‐Pan Wu
Abstract
Two pairs of chiral MOFs with hierarchical chiral structures were constructed through assembly of achiral AIE-type multidentate linkers and chiral camphoric acid. Non-reciprocal circularly polarized luminescence (CPL) can be observed on the macroscopic due to the coexistence of optical anisotropic and chiroptical nature. This study provides a new perspective to recognize and construct chiral crystalline materials.
Topics & Concepts
Chirality (physics)ReciprocalNanotechnologyChemistryMaterials scienceCombinatorial chemistryStereochemistryPhysicsChiral symmetryQuantum mechanicsQuarkLinguisticsPhilosophyNambu–Jona-Lasinio modelMetal-Organic Frameworks: Synthesis and ApplicationsMagnetism in coordination complexesChemical Synthesis and Reactions