Additive effects of rice husk-based carbon-silica composites on adsorption of diclofenac sodium and carbamazepine from aqueous solutions
Bettina Lilli, Susan Wassersleben, Tanja Schulze, Andreas Otto, Dirk Enke
Abstract
The present study investigated the adsorption of diclofenac sodium (DCF) and carbamazepine (CBZ) on carbon-silica composites (CSC), activated carbon (RH-AC) and biogenic silica (RH-BS) based on rice husks from aqueous solutions. The materials were characterised using scanning electron microscopy, infrared spectroscopy, inductively coupled plasma optical emission spectroscopy, nitrogen sorption and elemental analysis. These methods provided essential information on the morphology, chemical composition, textural properties and surface characteristics of porous materials. The results of the adsorption studies demonstrate that the investigated materials exhibit varying adsorption capacities for DCF and CBZ. The maximum adsorption capacity was achieved by CSCs, with 1111 mg g −1 for DCF and 455 mg g −1 for CBZ and indicates additive effects on the adsorption capacity of CSCs compared to RH-AC and RH-BS. In addition to the hydrogen bonds and the π-π electron donor-acceptor interactions of the carbon component, further hydrogen bonds are formed by the silanol groups of the silica component. The CSCs derived from rice husks represent an innovative approach to the more efficient removal of pharmaceutical residues from wastewater. This is accomplished by utilizing a single starting material for both components, thereby yielding a unique structural combination. • Rice husk-based adsorbents were used for adsorption of pharmaceuticals from aqueous solutions. • Rice husk-based adsorbents exhibit high sorption capacities for diclofenac sodium and carbamazepine. • Carbon-silica composites show an additive effect of adsorption of diclofenac sodium and carbamazepine. • Carbon-silica composites show higher affinity for diclofenac sodium adsorption than carbamazepine, due to molecular and hydrophobic interactions.