Decarboxylative Oxidation of Carboxylic Acids Using Photocatalysis and Copper Catalysis
Zhankui Sun, Muhammad Kashif Zaman, Shah Nawaz Khan, Yuanyuan Cai
Abstract
Abstract A decarboxylative oxidation of carboxylic acids was developed through visible-light-induced photocatalysis with molecular oxygen as a green oxidant and copper as a co-catalyst. This reaction worked smoothly on various type of acids, and could potentially be used in modifications of natural products. The high efficiency of this transformation was demonstrated on over 40 substrates.
Topics & Concepts
ChemistryPhotocatalysisCopperCatalysisMolecular oxygenDecarboxylationVisible spectrumOrganic chemistryOxygenCarboxylic acidPhotochemistryPhysicsOptoelectronicsOxidative Organic Chemistry ReactionsRadical Photochemical ReactionsCatalytic C–H Functionalization Methods