The Facile Dissociation of Carbon–Oxygen Bonds in CO<sub>2</sub>and CO on the Surface of LaCoSiH<sub><i>x</i></sub>Intermetallic Compound
Yongfang Sun, Yunlei Chen, Xiangyu Zhang, Yurong He, Zhongxian Qiu, Wentao Zheng, Fei Wang, Haijun Jiao, Yong Yang, Yongwang Li, Xiaodong Wen
Abstract
Abstract In catalysis science, the electronic structure of the active site determines the structure–activity relationship of the catalyst to a large extent. Therefore, modulating the electronic structure has become a main route for the rational design of metal‐based catalyst materials. In this work, we prepared a LaCoSiH x material that has more electronegativity and a lower workfunction than traditional supported Co‐based catalysts. Using CO 2 methanation as a model catalytic reaction, the facile dissociation of CO 2 and CO (a key reaction intermediate) on the surface of the LaCoSiH x catalyst is observed by various experimental methods (e.g., in situ Raman and FTIR) at room temperature. Moreover, theoretical calculation results further show that LaCoSiH x has a much stronger capacity for carbon–oxygen bond activation than the Co surface. The intrinsic mechanism is attributed to the marked electron transfer from catalysts into the antibonding orbital of CO 2 and CO.