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All‐cellulose composites prepared by partially dissolving cellulose using <scp>NaOH</scp>/thiourea aqueous solution

Fuqiang Hu, Miaolin Wang, Na Wang, Yucheng Hu, Meixue Gan, Danqing Liu, Yimin Xie, Qinghua Feng

2021Journal of Applied Polymer Science14 citationsDOI

Abstract

Abstract All‐cellulose composites (ACCs) were prepared by partially dissolving cellulose in the filter paper using NaOH/thiourea aqueous solution. The effects of dissolution time, thiourea ratio, and temperature on the properties of ACCs were investigated. ACCs were characterized by scanning electron microscope, attenuated total reflectance Fourier transform infrared spectroscopy, Raman spectroscopy, X‐ray diffraction, and tensile tests. The results revealed that the fibers in ACCs were tightly intertwined. The crystalline form of cellulose in ACCs was transformed from type I to type I/II mixture, and the crystallinity decreased from 77.32 to 51.40%. The tensile strength of ACCs was remarkably improved to 23.16 MPa. The results confirmed ACCs had a high potential for practical applications in the packaging field.

Topics & Concepts

CrystallinityCelluloseThioureaMaterials scienceUltimate tensile strengthAqueous solutionDissolutionFourier transform infrared spectroscopyRaman spectroscopyScanning electron microscopeChemical engineeringComposite materialCellulose fiberNuclear chemistryPolymer chemistryFiberChemistryOrganic chemistryOpticsEngineeringPhysicsAdvanced Cellulose Research StudiesLignin and Wood ChemistryNanocomposite Films for Food Packaging