(P,C)-cyclometalated complexes derived from naphthyl phosphines: versatile and powerful tools in organometallic chemistry
Julien Monot, Enrico Marelli, Blanca Martín‐Vaca, Didier Bourissou
Abstract
(P,C)M] complexes have also proved to be competent and actually competitive catalysts in several transformations, and they act as key intermediates in some others. In addition, interesting phosphorescence properties have been occasionally pointed out.
Topics & Concepts
TransmetalationChemistryMetallacycleTransition metalOxidative additionCatalysisOrganometallic chemistryChelationMetalCrystal structureStoichiometryGroup 2 organometallic chemistryCombinatorial chemistryCrystallographyStereochemistryX-ray crystallographyMoleculeOrganic chemistryDiffractionOpticsPhysicsOrganometallic Complex Synthesis and CatalysisCatalytic C–H Functionalization MethodsCatalytic Cross-Coupling Reactions