Transforming Metal–Organic Frameworks into Porous Liquids via a Covalent Linkage Strategy for CO<sub>2</sub> Capture
Dechao Wang, Yangyang Xin, Xiaoqian Li, Hailong Ning, Yudeng Wang, Dongdong Yao, Yaping Zheng, Zhuoyue Meng, Zhiyuan Yang, Yuting Pan, Peipei Li, Hongni Wang, Zhongjie He, Wendi Fan
Abstract
selective capture sites were determined by grand canonical Monte Carlo (GCMC) simulation. Furthermore, the universality of the covalent linkage surface engineering strategy was confirmed using different classes of oligomer species and another MOF (ZIF-8-bearing amino groups). Notably, this strategy can be extended to construct other PLs by taking advantages of the rich library of oligomer species, thus making PLs promising candidates for further applications in energy and environment-related fields, such as gas capture, separation, and catalysis.
Topics & Concepts
OligomerCovalent bondMaterials sciencePorosityLinkage (software)AdsorptionNanotechnologyChemical engineeringOrganic chemistryPolymer chemistryChemistryComposite materialEngineeringBiochemistryGeneMetal-Organic Frameworks: Synthesis and ApplicationsCovalent Organic Framework ApplicationsMembrane Separation and Gas Transport