Enhanced cocatalyst-free photocatalytic H<sub>2</sub> evolution by the synergistic AIE and FRET for an Ir-complex conjugated porphyrin
Kailin Zheng, Govardhana Babu Bodedla, Yuqi Hou, Jie Zhang, Runhui Liang, Jianzhang Zhao, David Lee Phillips, Xunjin Zhu
Abstract
A new Ir-complex conjugated porphyrin exhibits AIE property for the Ir-complex unit, inhibition of ACQ of the porphyrin unit and efficient energy transfer from the Ir-complex to the porphyrin, therefore, enhanced photocatalytic H 2 evolution.
Topics & Concepts
PorphyrinConjugated systemPhotochemistryFörster resonance energy transferPhotocatalysisChemistryMaterials scienceFluorescenceCatalysisOrganic chemistryPolymerOpticsPhysicsAdvanced Photocatalysis TechniquesNanocluster Synthesis and ApplicationsAdvanced Nanomaterials in Catalysis