Powder engineering of MXene-based heterojunction materials for photocatalysis and gas sensor applications
Vatra Reksa Ananda, Farah Nur Ramadhan, Azizah Mirza Kautsari, Tahta Amrillah, Angga Hermawan, Yoki Yulizar, Jarnuzi Gunlazuardi, Tohru Sekino, Shin‐ichi Orimo, Shu Yin
Abstract
MXene-based heterojunction materials have shown great promise in photocatalysis and sensing applications due to their unique structural and electronic properties. The synthesis of MXenes typically involves a top-down approach using MAX phase precursors, where the choice of etchants such as HF, LiF/HCl, or molten salts can significantly influence the surface termination, interlayer spacing, and defect density of the resulting MXenes. To further enhance the performance of MXenes, they are often combined with semiconductor materials to form heterojunction structures through various synthesis approaches, including self-assembly, ultrasonication, hydrothermal, and solvothermal methods. These heterostructures leverage the synergistic effects arising from the interface between MXenes and semiconductors, leading to improved charge separation, increased active sites, and enhanced adsorption capabilities, which are crucial for photocatalysis and sensing applications. The review highlights the critical role of powder engineering in the synthesis and performance optimization of MXene-based heterojunction materials, providing valuable insights for the continued advancement of these technologies.