Structural Stabilization and Superior Electrochemical Performance of Yttrium-Doped O3-NaFe<sub>0.4</sub>Ni<sub>0.3</sub>Mn<sub>0.3</sub>O<sub>2</sub> Cathodes for Sodium-Ion Batteries
Tingru Chen, Eugenio H. Otal, Tien Quang Nguyen, S. Narumi, Michihisa Koyama, Nobuyuki Zettsu
Abstract
This is the first demonstration of successful Y 3+ doping, and Y 3+ -doped O3-NaFe 0.4 Ni 0.3 Mn 0.3 O 2 (NaFNM) cathodes exhibit superior cyclability and C-rate capabilities. Y 3+ doping enabled cells with 91% capacity retention at 1 C after 100 cycles and a high specific capacity of 102 mA h g –1 at a 7 C rate. Furthermore, the full cell delivered outstanding cycling stability, with a capacity retention of 80% after 500 cycles at 1 C and 71.3% after 1000 cycles. Operando X-ray diffraction spectroscopy (XRD) and X-ray absorption spectroscopy, along with simulations using density functional theory and neural network potential methods, provided comprehensive insights on the effects of Y 3+ doping on the cycling characteristics. Our results confirm that Y 3+ doping effectively stabilizes the O3 structure, enhances the electrochemical performance, and addresses the challenge of irreversible O3 to P3 phase transitions.