Photoredox- and piezo-catalysed access to complex trifluoromethylated polycyclic structures from ynamides
Amal Lakhal, Maud Villeneuve, Laure Haberkorn, Jean‐Marie Fourquez, Jérémy Forté, Geoffrey Gontard, Louis Fensterbank, Cyril Ollivier
Abstract
Under photoredox- and piezo-catalysis conditions, ynamides undergo a radical to yield polycyclic compounds by fully utilizing the ynamide unsaturations.
Topics & Concepts
ChemistryYield (engineering)CatalysisPhotoredox catalysisCombinatorial chemistryPhotochemistryOrganic chemistryPhotocatalysisMetallurgyMaterials scienceFluorine in Organic ChemistrySulfur-Based Synthesis TechniquesCatalytic Alkyne Reactions