Excitation-Dependent Emission in Sb<sup>3+</sup>-Doped All-Inorganic Rare-Earth Double Perovskites for Anticounterfeiting Applications
Wenzhi Li, Yuxi Wang, Hong Yin, Junsheng Chen, Keli Han, Feng Liu, Ruiling Zhang
Abstract
Achieving high-efficiency tunable emission in a single phosphor remains a significant challenge. Herein, we report a series of Sb 3+ -doped all-inorganic double perovskites, Sb 3+:Cs 2 NaScCl 6, with efficient excitation-dependent emission. In 0.5%Sb 3+:Cs 2 NaScCl 6, strong blue emission with a high photoluminescence quantum yield (PLQY) of 85% is obtained under 265 nm light irradiation, which turns into bright neutral white light with a PLQY of 56% when excited at 303 nm. Spectroscopic and computational investigations were performed to reveal the mechanism of this excitation-dependent emission. Sb 3+ doping induces two different excitation channels: the internal transition of Sb 3+: 5s 2 → 5s5p and the electron transfer transition of Sb 3+: 5s → Sc 3+ 3d. The former one generates excited Sb 3+ ions, which can undergo efficient energy transfer to populate the host self-trapped exciton (STE) state, yielding enhanced blue emission. The latter one leads to the formation of a new STE state with the hole localized on Sb 3+ and the electron delocalized on the nearest Sc 3+, which accounts for the newly exhibited low-energy emission. The difference in the excitation pathways of the two emitting STE states results in the highly efficient excitation-dependent emission, making the doped systems promising anticounterfeiting materials.