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Naphthalene-based donor–acceptor covalent organic frameworks as an electron distribution regulator for boosting photocatalysis

Zeming Wang, Qiang Song, Cheng He, Pengyu Feng, Liang Zhao, Chunying Duan

2024Chemical Communications21 citationsDOI

Abstract

By incorporating the electron-rich naphthalene and electron-deficient triazine as an electron donor and an electron acceptor, a new donor-acceptor covalent organic framework as an electron distribution regulator was obtained for boosting photocatalytically oxidative coupling of benzylamines and selective oxidation of thioethers under the irradiation of green light (520 nm).

Topics & Concepts

Covalent bondElectron acceptorNaphthalenePhotocatalysisPhotochemistryChemistryAcceptorOxidative coupling of methaneElectron donorBoosting (machine learning)ElectronOrganic chemistryCatalysisComputer scienceCondensed matter physicsMachine learningPhysicsQuantum mechanicsCovalent Organic Framework ApplicationsAdvanced Photocatalysis TechniquesMetal-Organic Frameworks: Synthesis and Applications