Disentangling Cation and Anion Dynamics in Li<sub>3</sub>PS<sub>4</sub> Solid Electrolytes
Frazer N. Forrester, James A. Quirk, Theodosios Famprikis, James A. Dawson
Abstract
, we quantify the significant role of Li-Li correlation and anion dynamics in dominating Li-ion transport in this polymorph for the first time. The fundamental understanding and analysis presented herein is expected to be highly applicable to other solid electrolytes where the interplay between cation and anion dynamics is crucial to enhancing ion transport.
Topics & Concepts
Fast ion conductorIonElectrolyteMolecular dynamicsChemical physicsDiffusionChemistryMaterials scienceComputational chemistryPhysical chemistryThermodynamicsOrganic chemistryElectrodePhysicsAdvancements in Battery MaterialsAdvanced Battery Materials and TechnologiesAdvanced Battery Technologies Research