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Synthesis and opto-electronic properties of green light emitting metal Schiff base complexes

Prashant Nayak, H. S. Bhojya Naik, H.B. Teja, B.R. Kirthan, R. Viswanath

2021Molecular Crystals and Liquid Crystals19 citationsDOI

Abstract

Schiff base copper complex for OLEDs application was synthesized and ligand was characterized by NMR, mass spectroscopy, FTIR, and powder XRD. Photo-physical properties were recorded on UV-visible and photoluminescence spectroscopy. Their phosphorescent emissive-layer in green light emitting multi-layered OLED device was investigated. It exhibits CIE chromaticity color coordinates at x = 0.377 and y = 0.583. The maximum brightness, current efficiency and power efficiency for the 3.0 weight% Cu(II) complex doped electroluminescent device are 6436 cd/m2, 15.4 cd/A and 6.7 lm/W, respectively. These results opens the route for the development of cost-effective metal complex for Opto-electronic applications as a part of strong electroluminescent materials.

Topics & Concepts

ElectroluminescencePhosphorescenceSchiff baseChromaticityOLEDMaterials sciencePhotoluminescenceFourier transform infrared spectroscopyPhotochemistrySpectroscopyGreen-lightBrightnessCopperMetalOptoelectronicsFluorescenceLayer (electronics)ChemistryPolymer chemistryOpticsNanotechnologyMetallurgyQuantum mechanicsBlue lightPhysicsOrganic Light-Emitting Diodes ResearchMagnetism in coordination complexesMolecular Junctions and Nanostructures
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