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Integrated quantitative PIXE analysis and EDX spectroscopy using a laser-driven particle source

Francesco Mirani, Alessandro Maffini, Francesco Casamichiela, Andrea Pazzaglia, Arianna Formenti, D. Dellasega, Valeria Russo, D. Vavassori, D. Bortot, M. Huault, G. Zeraouli, V. Ospina, S. Malko, Jon Imanol Apiñaniz, J. A. Pérez-Hernández, D. De Luis, G. Gatti, L. Volpe, A. Pola, M. Passoni

2021Science Advances43 citationsDOIOpen Access PDF

Abstract

Among the existing elemental characterization techniques, particle-induced x-ray emission (PIXE) and energy-dispersive x-ray (EDX) spectroscopy are two of the most widely used in different scientific and technological fields. Here, we present the first quantitative laser-driven PIXE and laser-driven EDX experimental investigation performed at the Centro de Láseres Pulsados in Salamanca. Thanks to their potential for compactness and portability, laser-driven particle sources are very appealing for materials science applications, especially for materials analysis techniques. We demonstrate the possibility to exploit the x-ray signal produced by the co-irradiation with both electrons and protons to identify the elements in the sample. We show that, using the proton beam only, we can successfully obtain quantitative information about the sample structure through laser-driven PIXE analysis. These results pave the way toward the development of a compact and multifunctional apparatus for the elemental analysis of materials based on a laser-driven particle source.

Topics & Concepts

Particle (ecology)Characterization (materials science)LaserElemental analysisSpectroscopyMaterials scienceSample (material)Laser-induced breakdown spectroscopyAnalytical Chemistry (journal)MineralogyNanotechnologyOpticsChemistryPhysicsGeologyEnvironmental chemistryChromatographyInorganic chemistryAstronomyOceanographyX-ray Spectroscopy and Fluorescence AnalysisIon-surface interactions and analysisNuclear Physics and Applications
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