Mechanistic insights into CeO<sub>2</sub>-catalyzed direct synthesis of diethyl carbonate from CO<sub>2</sub> and ethanol assisted by zeolite and 2,2-diethoxypropane
Tao Chang, Mizuho Yabushita, Yoshinao Nakagawa, Norihisa Fukaya, Jun‐Chul Choi, Takayoshi Mishima, Seiji Matsumoto, Satoshi Hamura, Keiichi Tomishige
Abstract
A mechanistic study on the production of diethyl carbonate on a CeO 2 catalyst assisted by H-FAU and 2,2-diethoxypropane was conducted based on detailed kinetics.
Topics & Concepts
CatalysisDiethyl carbonateZeoliteCarbonateEthanolChemistryKineticsChemical engineeringOrganic chemistryPhysical chemistryEthylene carbonatePhysicsEngineeringElectrodeElectrolyteQuantum mechanicsCarbon dioxide utilization in catalysisCatalysis for Biomass ConversionAsymmetric Hydrogenation and Catalysis