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Gelatin-Coated Copper-Based Metal–Organic Framework for Controlled Insulin Delivery: Possibility toward Oral Delivery System

Pawan Kumar, Navpreet Kaur, Pranav Tiwari, Anoop K. Gupta, Shaikh M. Mobin

2023ACS Materials Letters21 citationsDOI

Abstract

The development of nontoxic, hemocompatible materials for controlled insulin delivery is a great challenging task for researchers. Herein, we demonstrate the design of a novel linker 5,5′-((pyridine-2,6-diylbis(methylene)) bis(oxy))diisophthalic acid (H 4 L) and its utilization to synthesize a new Cu-MOF (IITI-3) . IITI-3 crystallizes in a tetragonal crystal system with space group I 4/ mmm and shows a high Brunauer–Emmett–Teller (BET) surface area of 1026.5 m 2 /g with pore diameter (Barrett–Joyner–Halenda pore size distribution) of 3.413 nm. The IITI-3 is found to be stable in the biological fluid pH ranges from 3 to 10. Moreover, IITI-3 were explored for insulin delivery by coating the IITI-3 with gelatin ( [email protected] ); the overall insulin was controlled from the framework. The obtained result paves a new avenue for the oral delivery of insulin using the IITI-3 metal-organic framework.

Topics & Concepts

GelatinTetragonal crystal systemCopperMetal-organic frameworkDelivery systemLinkerInsulinMaterials scienceMetalNanotechnologyChemistryChemical engineeringBiomedical engineeringCrystal structureCrystallographyComputer scienceMetallurgyOrganic chemistryInternal medicineMedicineAdsorptionOperating systemEngineeringMetal-Organic Frameworks: Synthesis and ApplicationsDendrimers and Hyperbranched PolymersNanoplatforms for cancer theranostics
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