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Boosting classical and quantum nonlinear processes in ultrathin van der Waals materials

Xiaodan Lyu, Leevi Kallioniemi, Hongbing Cai, Liheng An, Ruihuan Duan, Shuin Jian Wu, Qinghai Tan, Chusheng Zhang, Ruihua He, Yansong Miao, Zheng Liu, Alexander Ling, J. Zúñiga‐Pérez, Weibo Gao

2025Nature Communications10 citationsDOIOpen Access PDF

Abstract

Abstract Understanding and controlling nonlinear processes is crucial for engineering light-matter interaction and generating non-classical light. A significant challenge in ultra-thin nonlinear materials is the marked diminution of the nonlinear conversion efficiency due to the reduced light-matter interaction length and, in many cases, the centrosymmetric crystalline structures. Here we relax these limitations and report a giant boost of classical and quantum nonlinear processes in ultrathin van der Waals materials. Specifically, with a metal-nonlinear material heterostructure we enhance classical second-harmonic generation in h-BN flakes by two orders of magnitude. Moreover, we have engineered a metal-SiO 2 -nonlinear material heterostructure resulting in a remarkable two orders of magnitude augmentation of the quantum spontaneous parametric down-conversion (SPDC) in NbOCl 2 flakes. Notably, we demonstrate SPDC in a 16 nm-thick NbOCl 2 flake integrated into the proposed structure. These findings simplify on-chip quantum state engineering and accelerate the use of van der Waals materials in nonlinear optoelectronics.

Topics & Concepts

van der Waals forceNonlinear systemQuantumHeterojunctionMaterials scienceNanotechnologyParametric statisticsPhysicsCondensed matter physicsOptoelectronicsChemical physicsQuantum mechanicsMoleculeMathematicsStatisticsAdvanced Fiber Laser TechnologiesPlasmonic and Surface Plasmon ResearchMechanical and Optical Resonators
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