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Synthesis of Porous Biochar Containing Graphitic Carbon Derived From Lignin Content of Forestry Biomass and Its Application for the Removal of Diclofenac Sodium From Aqueous Solution

Nguyễn Thị Tâm, Yun-guo Liu, Hassan Bashir, Peng Zhang, Shaobo Liu, Xiaofei Tan, Mingyang Dai, Meifang Li

2020Frontiers in Chemistry43 citationsDOIOpen Access PDF

Abstract

at 298 K, pH = 6.5). The effects of ambient conditions such as contact time, solution pH, temperature, ionic strength, electrolyte background on the uptake of DCF were investigated by a batch adsorption experiment. Results indicated that the experimental data were best fitted with the pseudo second-order model and Langmuir isotherm model. Furthermore, the adsorption of DCF onto the LPGC process was spontaneous and endothermic. Electrostatic interaction, H-bonding interaction, and π-π interaction are the possible adsorption mechanisms. The porous biochar containing graphitic carbon obtained from the lignin content of pitch pine sawdust may be a potential material for eliminating organic pollutants from water bodies.

Topics & Concepts

BiocharAqueous solutionCarbonizationAdsorptionSpecific surface areaPyrolysis2,4-DichlorophenolChemistryChemical engineeringBET theoryLangmuir adsorption modelLigninSulfuric acidNuclear chemistryMaterials scienceInorganic chemistryCatalysisOrganic chemistryEngineeringBacteriaGeneticsBiologyAdsorption and biosorption for pollutant removalNanomaterials for catalytic reactionsCovalent Organic Framework Applications