Novel Sb−SnO<sub>2</sub> Electrode with Ti<sup>3+</sup> Self‐Doped Urchin‐Like Rutile TiO<sub>2</sub> Nanoclusters as the Interlayer for the Effective Degradation of Dye Pollutants
Shuaishuai Man, Zehao Yin, Shanbin Zhou, Emmanuel Pameté, Lei Xu, Hebin Bao, Wenjing Yang, Zhihong Mo, Volker Presser, Xueming Li
Abstract
Abstract Stable and efficient SnO 2 electrodes are very promising for effectively degrading refractory organic pollutants in wastewater treatment. In this regard, we firstly prepared Ti 3+ self‐doped urchin‐like rutile TiO 2 nanoclusters (TiO 2‐ x NCs) on a Ti mesh substrate by hydrothermal and electroreduction to serve as an interlayer for the deposition of Sb−SnO 2 . The TiO 2‐ x NCs/Sb−SnO 2 anode exhibited a high oxygen evolution potential (2.63 V vs. SCE) and strong ⋅OH generation ability for the enhanced amount of absorbed oxygen species. Thus, the degradation results demonstrated its good rhodamine B (RhB), methylene blue (MB), alizarin yellow R (AYR), and methyl orange (MO) removal performance, with the rate constant increased 5.0, 1.9, 1.9, and 4.7 times, respectively, compared to the control Sb−SnO 2 electrode. RhB and AYR degradation mechanisms are also proposed based on the results of high‐performance liquid chromatography coupled with mass spectrometry and quenching experiments. More importantly, this unique rutile interlayer prolonged the anode lifetime sixfold, given its good lattice match with SnO 2 and the three‐dimensional concave–convex structure. Consequently, this work paves a new way for designing the crystal form and structure of the interlayers to obtain efficient and stable SnO 2 electrodes for addressing dye wastewater problems.