Design of Bowl‐Shaped <i>N</i>‐Hydroxyimide Derivatives as New Organoradical Catalysts for Site‐Selective C(sp<sup>3</sup>)−H Bond Functionalization Reactions
Terumasa Kato, Keiji Maruoka
Abstract
Abstract A series of new bowl‐shaped N ‐hydroxyimide derivatives has been designed and used as selective organoradical catalysts. A number of these bowl‐shaped N ‐hydroxyimide derivatives exhibit excellent site‐selectivity in the amination of benzylic C(sp 3 )−H bonds in aromatic hydrocarbon substrates.
Topics & Concepts
AminationCatalysisSurface modificationSelectivityHydrocarbonChemistryMedicinal chemistryCombinatorial chemistryOrganic chemistryStereochemistryPolymer chemistryPhysical chemistrySynthesis and Catalytic ReactionsCatalytic C–H Functionalization MethodsOxidative Organic Chemistry Reactions