Transforming electron-rich hetero-buckybowls into electron-deficient polycycles
Zhe Liu, Zhe Liu, Wenru Song, Chaoxian Yan, Zitong Liu, Zitong Liu, Hao‐Li Zhang, Xiangfeng Shao
Abstract
Oxidation of trichalcogenasumanenes ( TCS s) with NO species results in the simultaneous formation of ortho -quinone and diester groups. This reaction enables the transformation of electron-rich TCS s into electron-deficient polycycles.
Topics & Concepts
ChemistryElectronQuinoneTransformation (genetics)PhotochemistryMedicinal chemistryCrystallographyStereochemistryBiochemistryPhysicsQuantum mechanicsGeneOrganic Chemistry Cycloaddition ReactionsPorphyrin and Phthalocyanine ChemistrySynthesis and Properties of Aromatic Compounds