Litcius/Paper detail

Terahertz Spectroscopy of Emerging Materials

Jacob A. Spies, Jens Neu, Uriel Tayvah, Matt D. Capobianco, Brian Pattengale, Sarah Ostresh, Charles A. Schmuttenmaer

2020The Journal of Physical Chemistry C109 citationsDOI

Abstract

Over the past few decades, terahertz (THz) spectroscopy has become an established technique for studying the dielectric and transient photoconductive properties of materials. THz spectroscopy is a contact-free probe of electrical conductivity with subpicosecond time resolution, and it has proven especially useful for studying emerging materials. We highlight recent work used to study metal halide perovskites, metal oxides, metal–organic frameworks, and 2D materials in addition to providing an overview of methods in pump–probe THz spectroscopy. We focus on the ways in which THz spectroscopy can be used to study charge transport mechanisms and factors that might limit carrier mobility in emerging materials. This Perspective will provide a general understanding of pump–probe THz spectroscopy and how it can be applied to next-generation materials and will identify challenges and advantages in data processing to extract broadband complex conductivity spectra.

Topics & Concepts

Terahertz radiationSpectroscopyTerahertz spectroscopy and technologyMaterials scienceConductivityBroadbandOptoelectronicsNanotechnologyOpticsChemistryPhysicsPhysical chemistryQuantum mechanicsPerovskite Materials and ApplicationsTerahertz technology and applicationsAdvanced Thermoelectric Materials and Devices