Litcius/Paper detail

Customized Chiral Colloids

Mingzhu Liu, Fangyuan Dong, Nicolle S. Jackson, Michael D. Ward, Marcus Weck

2020Journal of the American Chemical Society34 citationsDOIOpen Access PDF

Abstract

This contribution describes a synthetic strategy for the fabrication of multicomponent colloidal "molecules" with controllable complex morphologies and compositionally distinct lobes. Using 3-(trimethoxysilyl)propyl methacrylate (TPM) as the building block, the methodology enables a scalable bulk synthesis of customized chiral colloidal particles with geometric and compositional chirality by a sequential seeded growth method. The synthetic protocol presents a versatile platform for constructing colloidal molecules with multiple components having customized shapes and functionalities, with the potential to impact the design of chromatic patchy particles, colloidal swimmers, and chiral optical materials, as well as informing programmable assembly.

Topics & Concepts

ChemistryChirality (physics)ColloidNanotechnologyMoleculeMethacrylateFabricationColloidal particlePolymerCopolymerMaterials scienceOrganic chemistryPhysicsMedicineAlternative medicineChiral symmetry breakingPathologyNambu–Jona-Lasinio modelQuarkQuantum mechanicsPickering emulsions and particle stabilizationMicro and Nano RoboticsSurfactants and Colloidal Systems