Amorphous porous Fe-BTC prepared <i>via</i> the post-synthetic metal-ion metathesis of HKUST-1
Asong Byun, Dohyun Moon, Byeongchan Lee, Jinhee Park
Abstract
Post-synthetic metal-ion metathesis (PSMM) of CuZn-HKUST-1 with Fe 2+ /Fe 3+ affords Fe-BTC: an aperiodic, defect-rich, but porous material. The complete PSMM and Fe 2+ to Fe 3+ oxidation enriches metal-node disorder and enhances Lewis acidity.
Topics & Concepts
MetathesisPorosityMaterials scienceAmorphous solidMetalIonMetal-organic frameworkMetal ions in aqueous solutionChemical engineeringCrystallographyChemistryMetallurgyOrganic chemistryComposite materialPolymerizationAdsorptionPolymerEngineeringMetal-Organic Frameworks: Synthesis and ApplicationsMXene and MAX Phase MaterialsChemical Synthesis and Characterization